- In episode 4, this card appeared in Vellian Crowler's trenchcoat when he reveals to Chazz Princeton and his friends that he has many rare cards to give to him.
- In episode 14, Jinzo uses this card during his Duel against Jaden Yuki. When "Elemental Hero Bubbleman" attacks and destroys "Spirit Caller", Jinzo activates this card to reduce the Battle Damage he would take from the attack to 0. This card remained on the field until the duel was over.
- In episode 22, Bastion Misawa uses this card during his Duel against Jaden Yuki. He activates this card after Jaden summons "Elemental Hero Wildheart" Jaden then points out that this card won't affect his "Wildheart". Due to the effect of "Litmus Doom Swordsman", its ATK became 3000 due to its own effect. After Jaden equips "Wildheart" with "Cyclone Boomerang", "Wildheart" attacks "Litmus Doom Swordsman". "Litmus Doom Swordsman" then destroys "Wildheart", but this activates the effect of "Cyclone Boomerang" effect, destroying all Spells and Traps and inflicting 500 damage to Bastion for each card destroyed this way. Because of this, this card was destroyed and Bastion's Life Points dropped to 0, winning Jaden the duel.
- In episode 66, this card appears in a flashback Jaden has when he sees Wheeler as Bastion which makes Jaden remember his Duel against Bastion.
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